(R)-(+)-MeO-BIPHEP, SL-A101-1, (R)-(+)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl - Names and Identifiers
Name | (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
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Synonyms | (R)-(+)-MeO-BIPHEP (6,6'-Dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine) (6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphane) (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-diMethoxy-1,1'-biphenyl,(R)-MeO-BIPHEP (R)-(+)-MeO-BIPHEP, SL-A101-1, (R)-(+)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl (R)-(+)-MeO-BIPHEP, SL-A101-1, (R)-(+)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl
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CAS | 133545-16-1
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InChI | InChI=1/C38H32O2P2/c1-39-33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)38-34(40-2)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3 |
(R)-(+)-MeO-BIPHEP, SL-A101-1, (R)-(+)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl - Physico-chemical Properties
Molecular Formula | C38H32O2P2
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Molar Mass | 582.62 |
Melting Point | 213-216°C |
Boling Point | 651.1±55.0 °C(Predicted) |
Specific Rotation(α) | 101 º (C=0.3 IN TOLUENE) |
Flash Point | 438.5°C |
Vapor Presure | 4.05E-16mmHg at 25°C |
Appearance | crystal |
Color | off-white |
Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
MDL | MFCD03095430 |
Physical and Chemical Properties | WGK Germany:3 |
(R)-(+)-MeO-BIPHEP, SL-A101-1, (R)-(+)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl - Risk and Safety
WGK Germany | 3 |
FLUKA BRAND F CODES | 8-10-23 |
HS Code | 29319090 |
(R)-(+)-MeO-BIPHEP, SL-A101-1, (R)-(+)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl - Introduction
(R)-( )-(6,6 '-dimethoxybiphenyl-2, 2'-yl) bis (diphenylphosphine) is an organic compound with the chemical formula C40H34O2P2. It is a chiral compound with one chiral center in the positive (R) configuration.
This compound is commonly used as a chiral ligand in metal organic catalytic reactions. Its properties include solubility and melting point. Due to its chiral characteristics and the flexibility of the ligand structure, it can be used in a variety of catalytic reactions, such as asymmetric hydrogenation, asymmetric olefin addition and asymmetric rearrangement.
The preparation method of (R)-( )-(6,6 '-dimethoxybiphenyl-2, 2'-yl) bis (diphenylphosphine) is relatively complicated and generally requires a multi-step reaction. Commonly used methods are synthesis by nucleophilic substitution reactions, organic synthesis reactions, and dehydration reactions.
When using and handling (R)-( )-(6,6 '-dimethoxybiphenyl-2, 2'-yl) bis (diphenylphosphine), you need to pay attention to its safety. It is an organic compound that can be toxic and irritating. Therefore, it is necessary to wear appropriate personal protective equipment during operation to avoid direct contact with skin and inhalation of gas or solution. At the same time, care should be taken to avoid reacting with other organic substances or oxides during use and storage to avoid the risk of fire and explosion. Regarding the safe use and handling of (R)-( )-(6,6 '-dimethoxybiphenyl-2, 2'-yl) bis (diphenylphosphine), it is best to refer to the relevant safety data sheet and operating procedures according to the specific situation.
Last Update:2024-04-10 22:29:15